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Spiro Hydrocarbons

A "spiro union" is one formed by a single atom which is the only common member of two rings. A "free spiro union" is one constituting the only union direct or indirect between two rings senior. The common atom is designated as the "spiro atom". According to the number of spiro atoms present, the compounds are distinguished as monospiro-, dispiro-, trispirocompounds, etc. The following rules apply to the naming of compounds containing free spiro unions.

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Compounds: Method 1
Compounds: Method 2
Radicals

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This HTML reproduction of Sections A, B and C of IUPAC "Blue Book" is as close as possible to the published version [see Nomenclature of Organic Chemistry, Sections A, B, C, D, E, F, and H, Pergamon Press, Oxford, 1979. Copyright 1979 IUPAC.] If you need to cite these rules please quote this reference as their source.

Published with permission of the IUPAC by Advanced Chemistry Development, Inc., www.acdlabs.com, +1(416)368-3435 tel, +1(416)368-5596 fax. For comments or suggestions please contact [email protected]