ACD/Name

Parent Hydrides

R-2.1 Mononuclear Hydrides

The names of mononuclear hydrides of the elements for use as parents in substitutive nomenclature are given in Table 2. Many are formed systematically by combining the 'a' term of the element (with elision of the terminal "a") with the ending "-ane", for example, borane for BH3, silane for SiH4, etc. There are important exceptions: methane for CH4, oxidane for OH2, sulfane for SH2, selane for SeH2, etc., (see Table 2). The systematic alternatives to well established common names, e.g., azane for ammonia, oxidane for water, and chlorane, bromane, etc., for hydrogen chloride, bromide, etc., are necessary for naming some derivatives and for generating names of polynuclear homologues. If the bonding number of the element differs from the normal one as defined in R-1.1, the name of the hydrides is modified by affixing a symbol as instructed by R-1.1.

See Also:
R-2.0 Introduction
R-2.2 Acyclic Polynuclear Hydrides
R-2.3 Monocyclic Hydrides
R-2.4 Polycyclic Parent Hydrides
R-2.5 Substituent Prefix Names Derived from Parent Hydrides

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This HTML reproduction is as close as possible to the published version [see IUPAC, Commission on Nomenclature of Organic Chemistry. A Guide to IUPAC Nomenclature of Organic Compounds (Recommendations 1993), 1993, Blackwell Scientific publications, Copyright 1993 IUPAC]. If you need to cite these rules please quote this reference as their source.

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