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,
symmetrical monoazo compounds,
, are named by adding the prefix "azo-" to the name of the parent hydride, RH, and unsymmetrical monoazo compounds
, are named by
placing "-azo-" between the names of the parent hydrides RH and
. Unsymmetrical compounds in which the parent hydride, RH, bears a principal characteristic group are named as
derivatives of the parent hydride substituted by an organylazo group,
. Details of the application of these traditional rules, which are recognized as an acceptable alternative, are
given in the 1979 edition of the IUPAC Nomenclature of Organic Chemistry
(see Rule C-9.1).

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