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| Characteristic group |
Prefix | Cf. Rule |
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| -Br | Bromo | C-102.1 |
| -Cl | Chloro | C-102.1 |
| -ClO | Chlorosyl | C-106.2 |
| -ClO2 | Chloryl | C-106.2 |
| -ClO3 | Perchloryl | C-106.2 |
| -F | Fluoro | C-102.1 |
| -I | Iodo | C-102.1 |
| -IO | Iodosyl | C-106.1 |
| -IO2 | Iodyl (replacing iodoxy) | C-106.1 |
| -I(OH)2 | Dihydroxyiodo | C-106.3 |
| -IX2 | X may be halogen or a radical, and the prefix names are dihalogenoiodo, etc., or, for radicals, patterned on diacetoxyiodo |
C-106.3 |
| =N2 | Diazo | C-931.4 |
| -N3 | Azido | C-941.1 |
| -NO | Nitroso | C-851.1 |
| -NO2 | Nitro | C-852.1 |
| =N(O)OH | aci-Nitro | C-852.2 |
| -OR | R-oxy | C-205.1 |
| -SR | R-thio (similarly R-seleno and R-telluro) | C-514.1 |
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